Vinyl‐triazolium monomers: Versatile and new class of radically polymerizable ionic monomers
Identifieur interne : 004536 ( Main/Exploration ); précédent : 004535; suivant : 004537Vinyl‐triazolium monomers: Versatile and new class of radically polymerizable ionic monomers
Auteurs : Brian J. Adzima [États-Unis] ; Steve C. Taylor [États-Unis] ; Hongkun He [États-Unis] ; David R. Luebke [États-Unis] ; Krzysztof Matyjaszewski [États-Unis] ; Hunaid B. Nulwala [États-Unis]Source :
- Journal of Polymer Science Part A: Polymer Chemistry [ 0887-624X ] ; 2014-02-01.
Descripteurs français
- Pascal (Inist)
- Cinétique chimique, Composé de l'iminium, Effet substituant, Etude expérimentale, Imidazolium(vinyl) sel polymère, Liquide ionique, Liquide ionique polymère, Polymérisation masse, Polymérisation radicalaire, Polymérisation solution, Préparation, Stabilité thermique, Triazole dérivé polymère, Triazolium(vinyl) sel polymère, Vinylique dérivé polymère.
English descriptors
- KwdEn :
Abstract
A set of eight functional 4‐vinyl‐1,2,3‐triazolium monomers were synthesized using copper catalyzed azide‐alkyne 2 + 3 Hüisgen cycloaddition. These vinyl‐trizolium monomers readily polymerized via free radical polymerization. The physical properties of the vinyl‐triazolium based poly(ionic liquid)s (PILs) are strongly dependent on the pendant functional groups. These polymers were characterized for glass transition temperature (Tg), solubility, and the thermal decomposition. The vinyl‐triazolium based PILs offer an efficient route to highly functional PILs with the advantage of facile synthesis and the ability to incorporate many desirable functional moieties. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 417–423
Url:
DOI: 10.1002/pola.27016
Affiliations:
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Le document en format XML
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These vinyl‐trizolium monomers readily polymerized via free radical polymerization. The physical properties of the vinyl‐triazolium based poly(ionic liquid)s (PILs) are strongly dependent on the pendant functional groups. These polymers were characterized for glass transition temperature (Tg), solubility, and the thermal decomposition. The vinyl‐triazolium based PILs offer an efficient route to highly functional PILs with the advantage of facile synthesis and the ability to incorporate many desirable functional moieties. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 417–423</div></front></TEI><affiliations><list><country><li>États-Unis</li></country><region><li>Pennsylvanie</li></region><settlement><li>Pittsburgh</li></settlement></list><tree><country name="États-Unis"><region name="Pennsylvanie"><name sortKey="Adzima, Brian J" sort="Adzima, Brian J" uniqKey="Adzima B" first="Brian J." last="Adzima">Brian J. Adzima</name></region><name sortKey="Adzima, Brian J" sort="Adzima, Brian J" uniqKey="Adzima B" first="Brian J." last="Adzima">Brian J. Adzima</name><name sortKey="He, Hongkun" sort="He, Hongkun" uniqKey="He H" first="Hongkun" last="He">Hongkun He</name><name sortKey="Luebke, David R" sort="Luebke, David R" uniqKey="Luebke D" first="David R." last="Luebke">David R. Luebke</name><name sortKey="Matyjaszewski, Krzysztof" sort="Matyjaszewski, Krzysztof" uniqKey="Matyjaszewski K" first="Krzysztof" last="Matyjaszewski">Krzysztof Matyjaszewski</name><name sortKey="Matyjaszewski, Krzysztof" sort="Matyjaszewski, Krzysztof" uniqKey="Matyjaszewski K" first="Krzysztof" last="Matyjaszewski">Krzysztof Matyjaszewski</name><name sortKey="Nulwala, Hunaid B" sort="Nulwala, Hunaid B" uniqKey="Nulwala H" first="Hunaid B." last="Nulwala">Hunaid B. Nulwala</name><name sortKey="Nulwala, Hunaid B" sort="Nulwala, Hunaid B" uniqKey="Nulwala H" first="Hunaid B." last="Nulwala">Hunaid B. Nulwala</name><name sortKey="Nulwala, Hunaid B" sort="Nulwala, Hunaid B" uniqKey="Nulwala H" first="Hunaid B." last="Nulwala">Hunaid B. Nulwala</name><name sortKey="Taylor, Steve C" sort="Taylor, Steve C" uniqKey="Taylor S" first="Steve C." last="Taylor">Steve C. Taylor</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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